A head‐to‐head isomer of di‐μ‐pivalamidato‐κ4N,O‐bis[(1,10‐phenanthroline‐κ2N,N′)platinum(II)] dinitrate dihydrate |
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Authors: | Ken Sakai Mai Kurashima Norinobu Akiyama Naoki Satoh Takashi Kajiwara Tasuku Ito |
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Abstract: | In the title compound, Pt2(C5H10NO)2(C12H8N2)2](NO3)2·2H2O, the intradimer Pt—Pt distance is relatively short 2.8489 (17) Å], which must be due to the strong intramolecular π–π‐stacking interactions between the phenanthroline moieties. The dimers stack along the c axis, forming one‐dimensional columns in which very intriguing d–d, π–π and d–π interactions exist. Although the dimer–dimer Pt...Pt distances are very long 4.340 (2) and 4.231 (2) Å], some short interdimer Pt...C contacts leading to strong interdimer associations are found 3.325 (19) and 3.402 (19) Å]. |
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