A dimeric heteroleptic five‐coordinate zinc(II) complex containing a non‐motionally restricted N,N′‐heterocyclic ligand |
| |
Authors: | Dana M Hatch William F Wacholtz Joel T Mague |
| |
Abstract: | The title compound, bis(μ‐1,2‐benzenethiolato)‐1:2κ3S,S′:S′;2:1κ3S,S′:S′‐bis(2,2′‐bipyridine‐κ2N,N′)zinc(II)], Zn2(μ‐C6H4S2)2(C10H8N2)2], crystallizes with the dinuclear molecule located on a center of symmetry. The coordination geometry about the Zn atom is a modestly distorted trigonal bipyramid, with the axial ligating atoms at an angle of 170.81 (4)° and the angles in the equatorial plane in the range 112.94 (4)–129.95 (4)°. Weak π‐stacking interactions between bipyridine ligands on adjacent molecules interplanar spacing = 3.315 (3) Å] and a possible weak intermolecular C—H?S hydrogen bond (H?S = 2.84 Å) are seen in the crystal. |
| |
Keywords: | |
|
|