Bis{μ‐[6‐(hydroxymethyl)‐2‐pyridyl]methanolato‐κ3N,O:O}bis{[2,6‐bis(hydroxymethyl)pyridine‐κ3O,N,O′]copper(II)} diacetate |
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Authors: | Akhilesh Kumar Gupta Jinkwon Kim |
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Abstract: | The title dinuclear CuII complex, [Cu2(C7H8NO2)2(C7H9NO2)2](CH3COO)2, has been synthesized by the reaction of Cu(CH3COO)2·H2O with pdmH2 (pdmH2 is pyridine‐2,6‐diyldimethanol) in the presence of tetrabutylammonium hydroxide. The title complex contains a centrosymmetric Cu2O2 core and each CuII atom has distorted octahedral geometry. Molecular [Cu2(pdmH)2(pdmH2)]2+ cations are connected by hydrogen bonds involving the CH3COO− anions, forming one‐dimensional chains along the a axis. |
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