Synthesis and photoreactivity of 4,5-dithienyl[1,3]dithiol-2-ones |
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Authors: | Roberts-Bleming Susan J Davies Gemma L Kalaji Maher Murphy Patrick J Celli Angela Maria Donati Donato Ponticelli Fabio |
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Institution: | Department of Chemistry, University of Wales, Bangor Gwynedd LL57 2UW, UK. |
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Abstract: | Whereas irradiation of 4,5-dithiophen-2-yl1,3]dithiol-2-one leads to the expected 2,3,5,6-tetrathiophen-2-yl-1,4-dithiine product, similar reaction of thiophen-3-yl-substituted 1,3]dithiol-2-ones leads to thieno3,4-c]dithiines via a unique ring cleavage reaction. |
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