Convenient method for the rapid generation of highly active and enantioselective yttrium catalysts for asymmetric hydroamination |
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| Authors: | Hannedouche Jérôme Aillaud Isabelle Collin Jacqueline Schulz Emmanuelle Trifonov Alexander |
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| Affiliation: | Equipe de Catalyse Moléculaire, ICMMO, UMR CNRS 8182, Université Paris Sud 11, Bat 420, 91405, Orsay Cedex, France. jerome.hannedouche@icmo.u-psud.fr |
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| Abstract: | A facile method for the preparation of highly active and enantioselective yttrium precatalysts for asymmetric hydroamination of gem-disubstituted aminoalkenes, from the combination of YCl(3) or YCl(3)(THF)(3.5) with ligand (R)- and n-BuLi is described. |
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