首页 | 本学科首页   官方微博 | 高级检索  
     检索      


Heterogeneous dynamics at the glass transition in van der Waals liquids: Determination of the characteristic scale
Authors:S Merabia  D Long
Institution:(1) Laboratoire de Physique des Solides, Université de Paris XI, Bat. 510, 91405 Orsay Cédex, France, FR
Abstract:Recent experiments have demonstrated that the dynamics in liquids close to the glass transition temperature is strongly heterogeneous. The characteristic size of these heterogeneities has been measured to be a few nanometers at T g. We extend here a recent model for describing the heterogeneous nature of the dynamics which allows both to derive this length scale and the right orders of magnitude of the heterogeneities of the dynamics close to the glass transition. Our model allows then to interpret quantitatively small probes diffusion experiments. Received 29 March 2002 and Received in final form 11 November 2002 RID="a" ID="a"e-mail: long@lps.u-psud.fr
Keywords:PACS  64  70  Pf Glass transitions –  61  41  +e Polymers  elastomers and plastics –  68  15  +e Liquid thin films
本文献已被 PubMed SpringerLink 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号