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Modified g-C3N4/TiO2 nanosheets/ZnO ternary facet coupled heterojunction for photocatalytic degradation of p-toluenesulfonic acid (p-TSA) under visible light
Institution:1. School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116, PR China;2. Instituto de Tecnologia Quimica CSIC-UPV, Universitat Politecnica de Valencia, Valencia 46022, Spain;1. School of Materials Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China;2. Shanghai Innovation Institute for Materials, Shanghai 200093, China;1. National & Local Joint Engineering Research Center for Applied Technology of Hybrid Nanomaterials, Henan University, Kaifeng, 475004, China;2. Collaborative Innovation Center of Nano Functional Materials and Applications of Henan Province, Henan University, Kaifeng, 475004, China;3. College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, China;1. Department of Chemistry and Chemical Engineering, Syed Babar Ali School of Science and Engineering, Lahore University of Management Sciences, Lahore 54792, Pakistan;2. Institute of Chemistry, University of the Punjab, P.O. Box 54590, Lahore, Pakistan;3. Department of Materials Science and Nanotechnology Engineering, TOBB University of Economics and Technology, Ankara, Turkey;4. Max-Planck-Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Rhineland-Palatinate, Germany;1. Beijing Key Laboratory of Energy Safety and Clean Utilization, School of Renewable Energy, North China Electric Power University, Beijing 102206, China;2. School of Metallurgical and Ecological Engineering, University of Science & Technology Beijing, Beijing 100083, China
Abstract:Novel ternary nanocomposites with facet coupled structure were synthesized by using modified g-C3N4, TiO2 nanosheets and nano-ZnO. Nanosheet/nanosheet heterojunction structure was investigated by TEM, XPS and XRD. FT–IR and Nitrogen adsorption were illustrated for chemical/physical structure analyses. Solution of p-Toluenesulfonic acid (p-TSA) was chosen as target pollutant for visible light photodegradation and the excellent removal efficiency was achieved by this structurally modified g-C3N4/TiO2/ZnO hybrid. The visible light absorption improvement and quantum efficiency enhancement, which were testified by UV–vis DRS, PL and p-TSA photodegradation measurements, due to the facet coupled structure and appropriate quantity of modified g-C3N4 in the nanocomposites.
Keywords:Visible light irradiation  Nanocomposite  Photodegradation
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