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Utilization of ultrasonic irradiation as a green and effective strategy to prepare poly(N-vinyl-2-pyrrolidone)/modified nano-copper (II) oxide nanocomposites
Institution:1. Organic Polymer Chemistry Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran;2. Nanotechnology and Advanced Materials Institute, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran;1. King Abdulaziz City for Science and Technology–KACST, Nuclear Science Research Institute-NSRI, National Center for Irradiation Technology-NCIT, P. O. BOX 6086, Riyadh, 11442, Saudi Arabia;2. King Abdulaziz City for Science and Technology–KACST, Innovation and Industrialization Affairs, Saudi-Chinese Center for Technology Transfer-SCCTT, P. O. BOX 6086, Riyadh, 11442, Saudi Arabia;1. Department of Physics, Chaudhary Devi Lal University, Sirsa 125055, India;2. Department of Physics, Haryana College of Technology & Management, Kaithal 136027, India;3. Research & Development, Manav Rachana International University, Faridabad 121001, India;1. Huaiyin Insttute of Technology, School of Life Science and Food Engineering, Huaian, Jiangsu 223003, China;2. Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals, Nanjin Forestry University, Nanjing, Jiangu 210037, China;3. Jiangsu Provincial Engineering Laboratory for Biomass Conversion and Process Integration, Huaiyin Institute of Technology; Huaian 223003, China;4. Key Laboratory of Medicinal Exploitation and Utilization of Regional Resources, Huaiyin Institute of Technology, Huaian, Jiangsu 223003, China;5. Jiangsu Provincial Key Laboratory of Palygorskite Science and Applied Technology, Huaiyin Institute of Technology, Huaian 223003, China;1. College of Food Science and Technology, Huazhong Agricultural University/National R & D Branch Center for Conventional Freshwater Fish Processing (Wuhan), Wuhan, Hubei Province 430070, PR China;2. Collaborative Innovation Center for Efficient and Health Production of Fisheries in Hunan Province, Changde 415000, PR China
Abstract:The present paper describes the result of investigations into preparation of novel nanocomposites (NCs) based on poly(N-vinyl-2-pyrrolidone) (PVP) as a biocompatible polymer and modified copper (II) oxide nanoparticles (NPs) as a nano-filler. To achieve optimum NCs properties, different ratios of modified copper (II) oxide NPs (3, 5, and 7 wt%) were used to fabricate PVP NCs and also the ultrasonic irradiation was utilized to perform these processes as a fast and effective method. Subsequently, the structure of the obtained nanohybrids was characterized by various techniques. The suitable incorporation between PVP matrix and modified CuO NPs can be seen from the FT-IR spectra. The obtained NCs indicated an efficient thermal improvement in comparison to the pristine polymer. Also, the uniform dispersion of modified CuO NPs in the PVP matrix was detected by FE-SEM and EDX. According to UV absorption spectra, it is clear that these NCs can be used in UV protecting applications.
Keywords:Polymeric nanocomposite  Ultrasonic technique  Poly(N-vinyl-2-pyrrolidone)  Copper (II) oxide nanoparticles  Thermal properties
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