Efficient removal of crystal violet and methylene blue from wastewater by ultrasound nanoparticles Cu-MOF in comparison with mechanosynthesis method |
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| Affiliation: | 1. Tehran University of Medical Sciences, School of Public Health, Department of Environmental Health Engineering, Tehran, Islamic Republic of Iran;2. Tehran University of Medical Sciences, Institute for Environmental Research, Center for Solid Waste Research, Tehran, Islamic Republic of Iran;3. Tehran University of Medical Sciences, Institute for Environmental Research, Center for Air Pollution Research, Tehran, Islamic Republic of Iran;4. Mashhad University of Medical Sciences, School of Health, Department of Environmental Health Engineering, Health Sciences Research Center, Mashhad, Islamic Republic of Iran |
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| Abstract: | The present investigation reports the synthesis of CuBTC (BTC = 1,3,5-benzenetricarboxylate) metal–organic frameworks (MOFs) under solid-state conditions and ultrasound irradiation. Herein, we study uptake and release properties of crystal violet (CV) and methylene blue (MB) from ultrasound nano-CuBTC MOF in comparison with mechanosynthesis method (bulk structure). The ultrasound-assisted methods give a decrease in the surface area as calculated from the reduced nitrogen adsorption capability. In comparison, the uptake of guest molecules on ultrasound nano-CuBTC is remarkable and clearly exceeds that of bulk structure in the aqueous solution of guests. In bulk compound the channel length is increased so that the amount of adsorption is decreased a little. The small guest enters and leaves the cavity rapidly, whereas larger guests enter slowly due to their size relative to the size of the gaps in the capsule. As a result, the uptake and release of MB from CuBTC is faster than that of CV. |
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| Keywords: | Wastewater Nano Metal–organic framework Crystal violet Methylene blue |
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