Paramagnetic complexes of platinum and palladium with acetamide |
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| Authors: | Simone Durand Gérard Jugie Jean-Pierre Laurent |
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| Institution: | (1) Laboratoire de Chimie de Coordination du C.N.R.S., Associé à l'Université, Paul Sabatier, 205, route de Narbonne, 31400 Toulouse, France |
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| Abstract: | Summary Direct reaction of K2MCl4 (M=Pt or Pd) with acetamide leads reproducibly to complexes which can be formulated as Pt(C2H4ON)2Cl]n and Pd4(C2H4ON)7(OH)2. Analytical and spectroscopic (i.r., n.m.r. and e.p.r.) data support the existence of polynuclear structures involving bridging ligands and partially oxidized metal centres. |
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