The feasibility of producing MWCNT paper and strong MWCNT film from VACNT array |
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Authors: | Guanghui Xu Qiang Zhang Weiping Zhou Jiaqi Huang Fei Wei |
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Institution: | (1) Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing, 100084, China |
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Abstract: | This study sought to produce carbon nanotube (CNT) pulp out of extremely long, vertically aligned CNT arrays as raw materials.
After high-speed shearing and mixing nitric acid and sulfuric acid, which served as the treatment, the researchers produced
the desired pulp, which was further transformed into CNT paper by a common filtration process. The paper’s tensile strength,
Young’s modulus and electrical conductivity were 7.5 MPa, 785 MPa and 1.0×104 S/m, respectively, when the temperature of the acid treatment was at 110°C. Apart from this, the researchers also improved
the mechanical property of CNT paper by polymers. The CNT paper was soaked in polyethylene oxide, polyvinyl pyrrolidone, and
polyvinyl alcohol (PVA) solution, eventually making the CNT/PVA film show its mechanical properties, which increased, while
its electrical conductivity decreased. To diffuse the polymer into the CNT paper thoroughly, the researchers used vacuum filtration
to fabricate a CNT/PVA film by penetrating PVA into the CNT paper. After a ten-hour filtration, the tensile strength and Young’s
modulus of CNT/PVA film were 96.1 MPa and 6.23 GPa, respectively, which show an increase by factors of 12 and 7, respectively,
although the material’s electrical conductivity was lowered to 0.16×104 S/m. |
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Keywords: | PACS" target="_blank">PACS 81 40 Rs 81 05 Uw 81 05 Qk 81 07 De 82 35 Np |
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