Propriétés magnétiques du thulium à l'état de sesquioxyde et de métal entre 0 et 110 kOe et de 2 à 1560°K |
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Authors: | N Perakis F Kern |
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Institution: | (1) Laboratoire de Magnétochimie, Institut de Physique de l'Université de Strasbourg, Strasbourg |
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Abstract: | Tm2O3 obeys between 80 and 980°K the Curie-Weiss lawχA (T+25=7,08) withμ eff=7.56 Bohr magnetons, the theoretical value for Tm3+(J=6,g=7/6). In the behavior of the metal,χΛ(T-14)=7.45 between 80 and 1540°K, a contribution of the non-localized electrons should be considered at high temperatures. The susceptibility of the metal is maximum at 53°K, minimum near 35°K, and the behavior is antiferromagnetic between these two temperatures, ferromagnetic below 35°K. An additional transition occurs near 10°K, vanishing by cooling in a magnetic field. The effect of this cryomagnetic treatment on the magnetization and the remanence has been measured in six different cooling fields. The magnetization reaches 1.0 and 5.0 magnetons in 26.7 and 110 kOe (pulsed field) respectively, whereas the saturation for the ground state3H6 isgJ=7. |
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