Bifunctional organometallic catalysts involving proton transfer or hydrogen bonding |
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| Authors: | Grotjahn Douglas B |
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| Affiliation: | Department of Chemistry and Biochemistry, San Diego State University, 5500 Campanile Drive, San Diego, CA 92182-1030, USA. grotjahn@chemistry.sdsu.edu |
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| Abstract: | Inspired by the cooperativity displayed by metalloenzymes, bifunctional organometallic complexes featuring pendant basic functional groups are designed and evaluated as catalysts in reactions for which enzymes are not suited. Anti-Markovnikov hydration of terminal alkynes is the focus, as are hydrogen bonding and proton transfer facilitated by the pendant groups. |
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| Keywords: | cooperative effects homogeneous catalysis hydrogen bonds P ligands proton transfer |
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