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Asymmetric radical additions of trialkylboranes to 2H-azirine-3-carboxylates |
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| Authors: | Risberg Erik Fischer Andreas Somfai Peter |
| Institution: | KTH Chemistry, Organic Chemistry, KTH, S-100 44 Stockholm, Sweden. |
| Abstract: | Asymmetric additions of alkyl radicals, generated from R3B, to chiral 2H-azirine-3-carboxylates offer a new entry to enantio-enriched aziridines, and proceed with high diastereoselectivity when using 8-phenylmenthol as chiral auxiliary. |
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