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Asymmetric synthesis of macrocyclic binaphthol dimers using a Sonogashira coupling reaction
Authors:Toshiro Harada   Shin-ichiro Matsui   Tran Mai Thi Tuyet   Masanori Hatsuda   Shinji Ueda   Akira Oku  Motoo Shiro
Affiliation:

a Department of Chemistry and Materials Technology, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan

b Rigaku Corporation, Matsubara-cho 3-91-12, Akishima, Tokyo 196-0003, Japan

Abstract:Asymmetric synthesis of 24- and 26-membered macrocyclic binaphthol dimers was achieved by assembling a 3,3′-diethynyl-1,1′-bi-2-naphthol unit and 1,2- and 1,3-phenylene units with Sonogashira coupling reaction.
Keywords:
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