New diphosphine ligands based on diphenyl ether for the Pd-catalyzed CO/ethene copolymerization |
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| Authors: | Caporali Maria Müller Christian Staal Bastiaan B P Tooke Duncan M Spek Anthony L van Leeuwen Piet W N M |
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| Affiliation: | Department of Chemical Engineering and Chemistry, Technische Universiteit Eindhoven, P.O. Box 513, 5600 MB, Eindhoven, The Netherlands. |
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| Abstract: | The catalytic activity and selectivity of palladium(II) complexes of new, flexible bidentate ligands in the CO/ethene copolymerization reaction have been found to change considerably with the steric properties of the ligands. |
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