| CRYSTAL AND MOLECULAR STRUCTURE OF A DIPHENYL SULFOXIDE COMPLEX WITH CERIUM NITRATE, Ce(N0_3)_3[(C_6H_5)_2SO]_4 |
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| 基金项目： | Projects supported by the Science Fund of the Chinese Academy of Sciences |
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| 摘 要： | <正> The title complex crystallises in the triclinic, space group PT with two formula units in a unit cell of dimensions a=11.182(4), b=14.357(5), c=17.362(6) A and α= 84.08(3)°, β=72.79(3)°, r= 69.27(2)°, Dx=1.51 g.cm-3, V=2489.6(15) A3. The final index for 6319 observed reflections is 0.0274. The Ce3+ ion is coordinated by ten oxygen atoms with Ce-O distances varying from 2.469 to 2.706 A. The three nitrate groups are all bidentate ligands.
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CRYSTAL AND MOLECULAR STRUCTURE OF A DIPHENYL SULFOXIDE COMPLEX WITH CERIUM NITRATE,Ce(N0_3)_3[(C_6H_5)_2SO]_4 |
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| Abstract: | The title complex crystallises in the triclinic, space group PT with two formula units in a unit cell of dimensions a=11.182(4), b=14.357(5), c=17.362(6) A and α= 84.08(3)°, β=72.79(3)°, r= 69.27(2)°, Dx=1.51 g.cm-3, V=2489.6(15) A3. The final index for 6319 observed reflections is 0.0274. The Ce3+ ion is coordinated by ten oxygen atoms with Ce-O distances varying from 2.469 to 2.706 A. The three nitrate groups are all bidentate ligands. |
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