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Thermodynamics of vapour adsorption on heterogeneous microporous adsorbents
Authors:MichaŁ Rozwadowski  Roman Wojsz
Institution:(1) Institute of Chemistry, Nicholas Copernicus University, 87-100 Toruh, Poland
Abstract:Fundamental thermodynamic functions have been derived for equations of adsorption isotherms including structural heterogeneity connected with micropore dimensions. Good agreement has been achieved between values of the differential molar enthalpy of adsorption and values of the isosteric adsorption heats obtained experimentally.
Keywords:Adsorption  microporous adsorbents  active carbons  thermodynamic functions of adsorption
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