Thermodynamics of vapour adsorption on heterogeneous microporous adsorbents |
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Authors: | MichaŁ Rozwadowski Roman Wojsz |
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Institution: | (1) Institute of Chemistry, Nicholas Copernicus University, 87-100 Toruh, Poland |
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Abstract: | Fundamental thermodynamic functions have been derived for equations of adsorption isotherms including structural heterogeneity connected with micropore dimensions. Good agreement has been achieved between values of the differential molar enthalpy of adsorption and values of the isosteric adsorption heats obtained experimentally. |
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Keywords: | Adsorption microporous adsorbents active carbons thermodynamic functions of adsorption |
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