首页 | 本学科首页   官方微博 | 高级检索  
     


Random and cooperative sequential adsorption on infinite ladders and strips
Authors:J. W. Evans  R. S. Nord
Affiliation:(1) Ames Laboratory and Department of Mathematics, Iowa State University, 50011 Ames, Iowa;(2) Department of Chemistry, Eastern Michigan University, 48197 Ypsilanti, Michigan
Abstract:We analyze various processes where particles are added irreversibly and sequentially at the sites of infinite ladders or broader strips (i.e., on terraces) of adsorption sites. For ldquosufficiently narrowrdquo strips or ladders, exact solution in closed form is possible for a variety of processes. Often this is most naturally achieved by mapping the process onto an equivalent one-dimensional process typically involvingcompetitive adsorption. We demonstrate this procedure for sequential adsorption with nearest-neighbor exclusion on a 2×infin square ladder. For other select processes on strips ldquoslightly too broadrdquo for exact solution, ldquoalmost exactrdquo analysis is possible exploiting an empty-site shielding property. In this way, we determine a jamming coverage of 0.91556671 for random sequential adsorption of dimers on a 2×infin square ladder. For ldquobroaderrdquo strips, we note that the complexity of these problems quickly approaches that for infin×infin lattices.
Keywords:Random and cooperative sequential adsorption  jamming coverage  ladders  strips  shielding
本文献已被 SpringerLink 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号