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Synthesis and transformations of metallocycles
Authors:A. G. Ibragimov  L. O. Khafizova  L. G. Yakovleva  E. V. Nikitina  K. G. Satenov  L. M. Khalilov  U. M. Dzhemilev
Affiliation:(1) Institute of Petrochemistry and Catalysis, Academy of Sciences of the Republic of Bashkortostan and Ufa Research Center of the Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075 Ufa, Russian Federation
Abstract:A regioselective method for the synthesis of 3-alkylalumacyclopentanes and 2-alkyl-1,4-dialuminiobutanes by the reactions of α-olefins with EtAlCl2, ROAlCl2, R2NAlCl2, or Et2AlCl and the Mg−ClCH2CH2Cl−Cp2ZrCl2 (ZrCl4) system was developed. For Part 18, see Ref. 1. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 778–784, April, 1999.
Keywords:organoaluminum compounds  zirconium-containing catalysts  cycloalumination  olefins  magnesium  alkyl-, alkoxy-, and dialkylaminodihaloalanes
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