Synthesis and transformations of metallocycles |
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Authors: | A. G. Ibragimov L. O. Khafizova L. G. Yakovleva E. V. Nikitina K. G. Satenov L. M. Khalilov U. M. Dzhemilev |
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Affiliation: | (1) Institute of Petrochemistry and Catalysis, Academy of Sciences of the Republic of Bashkortostan and Ufa Research Center of the Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075 Ufa, Russian Federation |
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Abstract: | A regioselective method for the synthesis of 3-alkylalumacyclopentanes and 2-alkyl-1,4-dialuminiobutanes by the reactions of α-olefins with EtAlCl2, ROAlCl2, R2NAlCl2, or Et2AlCl and the Mg−ClCH2CH2Cl−Cp2ZrCl2 (ZrCl4) system was developed. For Part 18, see Ref. 1. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 778–784, April, 1999. |
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Keywords: | organoaluminum compounds zirconium-containing catalysts cycloalumination olefins magnesium alkyl-, alkoxy-, and dialkylaminodihaloalanes |
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