Structural variability in neptunium(V) oxalate compounds: synthesis and structural characterization of Na2NpO2(C2O4)OH.H2O |
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Authors: | Bean Amanda C Garcia Eduardo Scott Brian L Runde Wolfgang |
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Affiliation: | Nuclear Materials and Chemistry Divisions, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA. bean@lanl.gov |
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Abstract: | Reaction of a (237)Np(V) stock solution in the presence of oxalic acid, calcium chloride, and sodium hydroxide under hydrothermal conditions produces single crystals of a neptunium(V) oxalate, Na(2)NpO(2)(C(2)O(4))OH.H(2)O. The structure consists of one-dimensional chains running down the a axis and is the first example of a neptunium(V) oxalate compound containing hydroxide anions. |
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