On the formation mechanism of hexafluoropropylene oxide in low-temperature liquid-phase oxidation of hexafluoropropylene by molecular oxygen |
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| Authors: | V. V. Shapovalov and V. A. Poluektov |
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| Affiliation: | (1) Research Institute of Physical Chemistry, 249020 Obninsk, Russia |
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| Abstract: | The effect of initiation rate (dose-rate of  -radiation) on the formation rate of hexafluoropropylene oxide has been studied. Experimental data confirm that the epoxide forms in the reaction R–O–C3F6· R·+C3F6O, as contrasted to the generally accepted fragmentation of  -peroxyalkyl radicals R–O–O–C3F6·RO·+C3F6O.
                 (    -)      .  ,    ,  R–O–C3F6R+C3F6O  R–O–O–C3F6RO+C3F6O.
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