A Facile Procedure for Conjugate Addition of Amines to Electron Deficient Alkenes with Metal Oxide as Catalyst |
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| Authors: | LIANG Xue-zheng GAO Shan YANG Jian-guo |
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| Institution: | [1]Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, Shanghai 200062, P. R. China [2]Energy Institute, Department of Materials Science and Engineering, Pennsylvania State University, PA 16802, USA |
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| Abstract: | A novel efficient procedure has been developed for the conjugate addition of amines to electron deficient alkenes. A series of metal oxides was synthesized for catalyzing the conjugate addition of amines and alkenes. After optimizing the reaction conditions, SrO was chosen as the most efficient catalyst for the reactions. The results show that the catalyst is very efficient for the conjugate addition of amines to electron deficient alkenes with the excellent yields in several minutes. Operational simplicity... |
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| Keywords: | Heterogeneous Conjugate addition Chemoselective Metal oxide Solvent-free |
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