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Studies on the Synthesis and Complexing Behavior of Crown Ethers with External Coordination Center
作者姓名:Jing Chao TAO  Yang Jie WU*  Shang Jie XU  Da Peng ZOU
作者单位:Jing Chao TAO,Yang Jie WU*,Shang Jie XU,Da Peng ZOU Department of Chemistry,Zhengzhou University,Zhengzhou 450052
基金项目:the National Natural Science Foundation of China (29872034) and the Natural Science Foundation of Henan Province for the financi
摘    要:Ligands capable of positioning two or more very different metal cations, like transition metal and alkali or alkaline earth metal cations, have been described recently1-3. Reinhoudt et al. have synthesized a number of ligands with the cavity for transition metal cations as well as the cavity for alkali metal cations and the corresponding comlexes with different kinds of metal ions4,5. It was anticipated that co-complexation of a hard cation closing to the complexed transition metal cation woul…


Studies on the Synthesis and Complexing Behavior of Crown Ethers with External Coordination Center
Jing Chao TAO,Yang Jie WU*,Shang Jie XU,Da Peng ZOU.Studies on the Synthesis and Complexing Behavior of Crown Ethers with External Coordination Center[J].Chinese Chemical Letters,2001(6).
Authors:Jing Chao TAO  Yang Jie WU  Shang Jie XU  Da Peng ZOU
Institution:Jing Chao TAO,Yang Jie WU*,Shang Jie XU,Da Peng ZOU Department of Chemistry,Zhengzhou University,Zhengzhou 450052
Abstract:The synthesis, characterization of five ditopic or tritopic crown compounds were reported in this paper together with the preparation of the corresponding hetero-dinuclear and hetero-trinuclear complexes with different metal cations.
Keywords:Polytopic crown ether  hetero-polynuclear complex  co-ordination  
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