<Superscript>2</Superscript>H and <Superscript>13</Superscript>C NMR investigation of deuterofullerites C<Subscript>60</Subscript>D<Subscript>x</Subscript>期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

2H and 13C NMR investigation of deuterofullerites C60Dx

Authors:	V.P.?Tarasov,Y.B.?Muravlev,V.N.?Fokin,Y.M.?Shulga author-information" > author-information__contact u-icon-before" > mailto:shulga@icp.ac.ru" title=" shulga@icp.ac.ru" itemprop=" email" data-track=" click" data-track-action=" Email author" data-track-label=" " >Email author

Affiliation:	(1) Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991 Moscow, Russia;(2) Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russia

Abstract:	Deuterofullerites C₆₀D_x have been studied by ²H and ¹³C NMR. These fullerites have two types of carbon–deuterium bonds: C–D terminal bonds, characterized by the quadrupole coupling constant (QCC) of 171 kHz, and –C ··· D ··· C– bridging bonds with a QCC of 56 kHz. The latter is responsible for the rigid lattice found in these fullerites, which is untypical of fullerenes. PACS 81.05.Tp; 82.56.Fk; 61.48.+c; 61.18.Fs; 61.10.Nz

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