Study of optical nonlinearity of functionalized multi-wall carbon nanotubes by using degenerate four wave mixing and Z-scan techniques |
| |
Authors: | Kailash C Jena MM Shaijumon S Ramaprabhu |
| |
Institution: | Department of Physics, Indian Institute of Technology Madras, Chennai 600 036, India |
| |
Abstract: | The phase conjugation geometry of degenerate four wave mixing (DFWM) technique has been employed to study the third-order optical nonlinear susceptibility (χ3) and second-order hyperpolarizability of multi-wall carbon nanotubes (MWCNTs). MWCNTs were grown by thermal chemical vapor deposition method and, subsequently functionalized with carboxylic acid group to improve their solubility in an organic solvent, ethylene glycol. The average hyperpolarizability for each carbon atom has been found to be 4.74 × 10−46 m5/V2 for the pump pulse of 8 ns at 532 nm. Decreasing the pulse width of the pump laser decreases the average value of hyperpolarizability. The absorption spectra show a monotonous increase from IR through visible and give an opportunity to estimate the imaginary part of the χ3 by the open aperture Z-scan technique. |
| |
Keywords: | 42 65 An 42 65 Hw 42 65&minus k 83 70 D |
本文献已被 ScienceDirect 等数据库收录! |