| Probing the Intact Cluster Catalysis Concept by Tetrahedral Clusters With Framework Chirality |
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| 作者姓名： | G. Süss-Fink |
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| 作者单位： | Institut de Chimie，Université de Neuchatel，CH-2007 Neuchatel，Switzerland，Institut de Chimie，Université de Neuchatel，CH-2007 Neuchatel，Switzerland |
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| 摘 要： | In order to bring evidence for or against the hypothesis of catalytic hydrogenation by intact trinuclear arene ruthenium clusters containing an oxo cap, the substrate being hydrogenated inside the hydrophobic pocket spanned by the three arene ligands （“supramolecular cluster catalysis”）, we synthesized cationic Ru30 clusters （See Fig. 1） with three different arene ligands （intrinsically chiral tetrahedra）.
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| 关 键 词： | 加氢催化 钌簇 催化剂 三环芳烃 配合基 |
| 文章编号： | 0427-7104（2005）05-0810-01 |
| 收稿时间： | 2005-06-03 |
| 修稿时间： | 2005-06-03 |
Probing the Intact Cluster Catalysis Concept by Tetrahedral Clusters With Framework Chirality |
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| G. Süss-Fink,L. Vieille-Petit.Probing the Intact Cluster Catalysis Concept by Tetrahedral Clusters With Framework Chirality[J].Journal of Fudan University(Natural Science),2005,44(5):810-810. |
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| Authors: | G Süss-Fink L Vieille-Petit |
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| Abstract: | |
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| Keywords: | catalytic hydrogenation ruthenium clusters framework chirality |
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