Copper(II) and cobalt(II) complexes with a chiral 5-pyrazolone derivative obtained from the terpene (+)-3-carene: Synthesis and properties |
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Authors: | Z A Savel’eva L A Glinskaya R F Klevtsova E G Boguslavskii S A Popov N V Semikolenova A V Tkachev V A Zakharov S V Larionov |
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Institution: | (1) Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia;(2) Vorozhtsov Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia;(3) Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090, Russia |
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Abstract: | The complexes CuLCl2] (I), CoLCl2] (II), and CuLBr2 (III) (where L is the derivative of optically active 5-pyrazolone prepared from the terpene (+)-3-carene) were obtained and characterized. According to X-ray diffraction data, crystal structures I and II (orthorhombic crystal system) are built from mononuclear acentric molecules. In the resulting complexes, the Cu2+ or Co2+ ion coordinates two N atoms of the chelating bidentate ligand L and two Cl atoms, thus making a distorted tetrahedron. Intermolecular contacts and the hydrogen bonds Cl(1)…H-O(1) give rise to columns parallel to axis y. For complexes I and III, μeff = 1.83 and 1.81 μB, respectively; these values correspond to the electronic configuration d 9 . For complex II, μeff = 4.42 μB, which suggests the tetrahedral structure of the coordination entity CoCl2N2. Complexes I and III were studied by EPR spectroscopy. |
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