| 长叶烯通过异构化,氧化和Prins反应合成新型香料 |
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| 引用本文： | 王植材 邓逊知. 长叶烯通过异构化,氧化和Prins反应合成新型香料[J]. 化学研究与应用, 1996, 8(3): 364-368 |
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| 作者姓名： | 王植材 邓逊知 |
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| 作者单位： | 中山大学化学系 |
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| 摘 要： | 本文报道综合利用长叶烯（１）催化异构化为异长叶烯（２）及合成系列香料的方法；通过氧化反应合成不同香型烯醇酯类等；Ｐｒｉｎｓ反应合成系列化合物。鉴定了１０种香料化合物的香型。
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| 关 键 词： | 长叶烯 异构化 氧化 prins反应 合成 香料 |
THE SYNTHESIS OF NEW ODOROUS SUBSTANCES BY ISOMERIZATION,OXIDATION & PRINS REACTION OF LONGIFOLENE |
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| Wang Zhicai,Deng Xunzhi,Wu Xiaolin,Jian Lasheng,Zheng Qihuang. THE SYNTHESIS OF NEW ODOROUS SUBSTANCES BY ISOMERIZATION,OXIDATION & PRINS REACTION OF LONGIFOLENE[J]. Chemical Research and Application, 1996, 8(3): 364-368 |
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| Authors: | Wang Zhicai Deng Xunzhi Wu Xiaolin Jian Lasheng Zheng Qihuang |
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| Abstract: | The methods of synthesis of isolongifolene from longifolene by the catalyzing isomerization and the formating of odorous substances were reported.The different fragnant enol esters were synthesized by the oxidating reaction and some odorous substances that are useful in future were synthesized by the Prins reaction.Ten pieces of odorous substances were defined. |
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| Keywords: | Longifoene Isomerization Oxidation Prins reaction Synthesis Odorous substances |
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