Phosphorimetric Determination of Polycyclic Aromatic Hydrocarbons in Clinoptilolite-Filled Fibers at Room Temperature |
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Authors: | G I Romanovskaya M V Koroleva V A Nikashina B K Zuev |
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Institution: | (1) Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, Moscow, 119991, Russia |
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Abstract: | The phosphorescence of polycyclic aromatic hydrocarbons (PAHs) adsorbed on natural zeolite (clinoptilolite) and clinoptilolite-filled acrylic fibers was studied at room temperature. The optimal conditions were selected for the phosphorescence of PAHs extracted from water and water–dioxane solutions at room temperature using clinoptilolite-filled fibers. The phosphorescence of PAHs in the clinoptilolite-filled fibers at room temperature is characterized by a high quantum yield and long lifetimes of PAH triplet states, as was the case at low temperatures (77 K). The results obtained indicate that the adsorbents used offer promise for the analytical chemistry of PAHs. |
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