| 以芳胺为电子给体的D-π-A有机光敏染料———— 染料敏化太阳电池中的应用 |
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| 引用本文： | 宋晓睿,王雪松,张宝文.以芳胺为电子给体的D-π-A有机光敏染料———— 染料敏化太阳电池中的应用[J].化学进展,2008,20(10):1524-1533. |
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| 作者姓名： | 宋晓睿 王雪松 张宝文 |
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| 作者单位： | （1. 中国科学院理化技术研究所 北京100080|2. 中国科学院研究生院 北京 100039) |
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| 摘 要： | 不含金属的有机染料在染料敏化太阳电池（DSC）中的应用愈加广泛，以芳胺为电子给体的D-π-A分子是其中重要的一类。本文依据芳香胺的结构，将近5年来应用于DSC中一百多个D-π-A分子分成四类，包括：基于N-烷基-苯胺的D-π-A光敏染料，基于三苯胺的D-π-A光敏染料，由包含芴基团的三芳胺构建的D-π-A光敏染料，包含芳胺基团的其它结构类型的D-π-A光敏染料。评述了它们的光电转换性能。
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| 关 键 词： | 染料敏化太阳电池 有机光敏染料 D-π-A分子 芳香胺 |
| 收稿时间： | 2008-01-21 |
| 修稿时间： | 2008-02-25 |
D-π-A Type Organic Photosensitizers with Aromatic Amine as Electron-Donating Group---- Application in Dye-Sensitized Solar Cells |
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| Song Xiaorui Wang Xuesong Zhang Baowen.D-π-A Type Organic Photosensitizers with Aromatic Amine as Electron-Donating Group---- Application in Dye-Sensitized Solar Cells[J].Progress in Chemistry,2008,20(10):1524-1533. |
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| Authors: | Song Xiaorui Wang Xuesong Zhang Baowen |
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| Institution: | (1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080, China|2. Graduate University of Chinese Academy of Sciences, Beijing 100039, China) |
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| Abstract: | Metal-free organic photosensitizers were widely used in dye-sensitized solar cells (DSCs), of which D-π-A molecules with aromatic amine as electron donor (D) represent one of the most important types. On the basis of the structures of the aromatic amine moiety, more than 100 D-π-A type organic photosensitizers utilized in DSCs over the past five years were classified into 4 categories, including D-π-A dyes based on N-alkyl-aniline, D-π-A dyes based on triphenylamine, D-π-A dyes based on fluorene-containing triphenylamine, and other types of aromatic amine-containing D-π-A dyes, and their photoelectric conversion properties are reviewed. |
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| Keywords: | dye-sensitized solar cells(DSCs) organic photosensitizer D-&pi -A molecule aromatic amine |
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