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Nitration of aromatic compounds under neutral conditions using the Ph2PCl/I2/AgNO3 reagent system
Authors:Najmeh Nowrouzi  Mohammad Zareh Jonaghani
Institution:Department of Chemistry, Faculty of Sciences, Persian Gulf University, Bushehr 75169, Iran
Abstract:Aromatic compounds were nitrated efficiently under essentially neutral conditions by employing Ph2PCl in the presence of I2 and AgNO3. This method minimizes waste products compared to traditional methods and gives the corresponding mononitro derivatives in good to excellent yields in dichloromethane at room temperature.
Keywords:Chlorodiphenylphosphine  Iodine  Nitration  Aromatic compounds
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