The easy hydrolysis of hexacyanocyclopropane, ethyl 1,2,2,3,3-pentacyanocyclopropane-1-carboxylate, 1,2,2,3,3-pentacyanocyclopropane-1-carboxamide, andN,N-dimethyl-1,2,2,3,3-pentacyanocyclopropane-1-carboxamide tor-1,c-2,c-3-tricyanocyclopropane-t-carboxamide |
| |
| Authors: | Siaka Sorho P M Lukin O E Nasakin V N Nesterov M Y Antipin V N Khrustalev |
| |
| Institution: | (1) Chuvash State University, 15 Moskovskii prosp., 428015 Cheboksary, Russian Federation;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
| |
| Abstract: | Hydrolysis of hexacyanocyclopropane (1a), ethyl 1,2,2,3,3-pentacyanocyclopropane-1-carboxylate (1b), 1,2,2,3,3-pentacyanocylopropane-1-carboxamide (1c), andN,N-dimethyl-1,2,2,3,3-pentacyanocylopropane-1-carboxamide (1d) in 95% acetic acid yieldsr-1,c-2,c-3-tricyanocyclopropane-t-1-carboxamide (3). The structure of3 was proved by X-ray diffraction analysis.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 454–456, March, 1998. |
| |
| Keywords: | hexacyanocyclopropane ethyl 1 2 2 3 3-pentacyanocyclopropane-1-carboxylate 1 2 2 3 3-pentacyanocyclopropane-1-carboxamide N N-dimethyl-1 2 2 3 3-pentacyanocyclopropane-1-carboxamide hydrolysis r-1 c-2 c-3-tricyanocyclopropane-t-1-carboxamide X-ray diffraction study |
| 本文献已被 SpringerLink 等数据库收录！ |
|
