Total synthesis of (+)-pederin. 2. Stereocontrolled synthesis of (+)-benzoylselenopederic acid and total synthesis of (+)-pederin |
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| Authors: | Tadashi Nakata Shigeto Nagao Takeshi Oishi |
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| Institution: | Riken (The Institute of Physical and Chemical Research) Wako-shi, Saitama 351-01, Japan |
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| Abstract: | (+)-Benzoylselenopederic acid (1), a left half of (+)-pederin (3), was synthesized stereoselectively based on the Zn(BH4)2 reduction and total synthesis of (+)-pederin (3) was accomplished from 1 and the previously synthesized 2. |
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