ESR Studies on N-Alkylphenothiazine Radical Cation Salts |
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Authors: | GUO Qing-xiang LIU Bo LIU You-cheng |
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Institution: | 1. Natioiial Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000;
2. Dept. of Modern Chem. , University of Science and Technology of China, Hefei, 230006 |
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Abstract: | he stable radical cation salts of phenothiazine and N-alkyl-phenothiazine(alkyl =methyl , ethyl , isohutyl , isopentyl and benzyl) hexachloroantimonate ,per-chlorate , and iodide were prepared by means of one-electron oxidation with 2 ,2 , 6 ,6-tetramethyl- 4-acetoxypiperidine oxoammonium hexachloroantimonate , perchloricacid, hydrogen peroxide, and molecular iodine, respectively. The radical cationswere characterized using ESR spectroscopy. Conformational analysis based on theESR parameters suggests that the radical cations adopt a planar configuration withthe nitrogen radical as the center. |
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Keywords: | Phenothiazine Radical cation salts ESR spectra |
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