Selective alcohol oxidation catalysed BY FeCl3 /novel glycine functionalised IONIC liquid |
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| Affiliation: | 1. PG and Research Department of Chemistry, Pachaiyappas College Campus, University of Madras Chennai, 600 030, India;2. Department of Chemistry, Pachaiyappas College for Women Campus, University of Madras, Kanchipuram, 631501, Tamilnadu, India |
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| Abstract: | An effective and eco-friendly technique were designated for quick alcohol oxidation by glycine functionalised imidazolium ionic liquids in presence of FeCl3 at ambient-temperature. No over the primary alcohols oxidation to carbonyl compounds was observed in presence of this FeCl3/[Gmim]Cl. These benefits of the catalyst resulted mainly from the circumstance with alcohols-H2O2, and the Fe3+ was coordinated by the immobilized IL to permitted both reactants to access the active sites of the catalyst effectively. The catalyst recycled nine times without loss of activity. |
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| Keywords: | Carbonyl compound Iron Green chemistry Peroxide Alcohol |
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