| 五氟乙基硫叶立德:一类新的亲电五氟乙基化试剂（英文） |
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| 引用本文： | 刘亚飞,葛航铭,吕龙,沈其龙.五氟乙基硫叶立德:一类新的亲电五氟乙基化试剂（英文）[J].有机化学,2019(1):257-264. |
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| 作者姓名： | 刘亚飞 葛航铭 吕龙 沈其龙 |
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| 作者单位： | 中国科学院上海有机化学研究所中国科学院有机氟化学重点实验室分子合成科学卓越研究中心中国科学院大学;中国科学院上海有机化学研究所 |
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| 基金项目： | Project supported by the National Natural Science Foundation of China(Nos.21625206,21632009,21572258,21572259,21421002);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000)~~ |
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| 摘 要： | 发展了两个基于硫叶立德骨架的亲电五氟乙基化试剂,其合成高效简洁、固体状态下稳定而溶液中反应活性高.在温和条件下,该试剂可以与β-酮酸酯、芳基/杂芳基碘化物以及富电子芳烃反应高产率地得到相应的五氟乙基化产物.
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| 关 键 词： | 氟 五氟乙基 硫叶立德 亲电 |
Pentafluoroethyl-Substituted Sulfonium Ylides: New Electrophilic Pentafluoroethylating Reagents |
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| Liu Yafei,Ge Hangming,Lu Long,Shen Qilong.Pentafluoroethyl-Substituted Sulfonium Ylides: New Electrophilic Pentafluoroethylating Reagents[J].Chinese Journal of Organic Chemistry,2019(1):257-264. |
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| Authors: | Liu Yafei Ge Hangming Lu Long Shen Qilong |
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| Institution: | (Key Laboratory of Organofluorine Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200032;Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032) |
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| Abstract: | Liu Yafei;Ge Hangming;Lu Long;Shen Qilong(Key Laboratory of Organofluorine Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200032;Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032) |
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| Keywords: | fluorine pentafluoroethyl sulfonium ylide electrophilic |
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