| 具有光热性能的碳龙配合物材料（英文） |
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| 引用本文： | 吴凡,黄文超,卓凯玥,华煜晖,林剑锋,何国梅,陈江溪,聂立铭,夏海平.具有光热性能的碳龙配合物材料（英文）[J].有机化学,2019(6):1743-1752. |
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| 作者姓名： | 吴凡 黄文超 卓凯玥 华煜晖 林剑锋 何国梅 陈江溪 聂立铭 夏海平 |
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| 作者单位： | 厦门大学材料学院材料科学与工程系;厦门大学公共卫生学院分子影像暨转化医学研究中心分子疫苗学和分子诊断学国家重点实验室;厦门大学化学化工学院化学系 |
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| 基金项目： | Project supported by the National Natural Science Foundation of China(Nos.21302158,U1705254,21490573)~~ |
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| 摘 要： | 金属有机化合物很少作为光热材料.报道一系列碳龙配合物的合成及其光热性能,将OsCl2(PPh3)3与有机多炔碳链反应获得金属杂戊搭炔,再与末端炔烃发生2+2]环加成反应得到此类碳龙配合物——锇杂戊搭烯并环丁二烯.这些共轭的金属杂环化合物在紫外-可见区具有宽吸收并表现出优异的光热性能,有望成为一类新型的光热材料.
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| 关 键 词： | 金属有机化合物 金属杂环 光热效应 |
Carbolong Complexes as Photothermal Materials |
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| Wu Fan,Huang Wenchao,Zhuo Kaiyue,Hua Yuhui,Lin Jianfeng,He Guomei,Chen Jiangxi,Nie Liming,Xia Haiping.Carbolong Complexes as Photothermal Materials[J].Chinese Journal of Organic Chemistry,2019(6):1743-1752. |
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| Authors: | Wu Fan Huang Wenchao Zhuo Kaiyue Hua Yuhui Lin Jianfeng He Guomei Chen Jiangxi Nie Liming Xia Haiping |
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| Institution: | (Department of Materials Science and Engineering,College of Materials,Xiamen University,Xiamen 361005;Department of Chemistry,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005;State Key Laboratory of Molecular Vaccinology and Molecular Diagnosis,Center for Molecular Imaging and Translational Medicine,School of Public Health,Xiamen University,Xiamen 361102) |
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| Abstract: | Wu Fan;Huang Wenchao;Zhuo Kaiyue;Hua Yuhui;Lin Jianfeng;He Guomei;Chen Jiangxi;Nie Liming;Xia Haiping(Department of Materials Science and Engineering,College of Materials,Xiamen University,Xiamen 361005;Department of Chemistry,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005;State Key Laboratory of Molecular Vaccinology and Molecular Diagnosis,Center for Molecular Imaging and Translational Medicine,School of Public Health,Xiamen University,Xiamen 361102) |
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| Keywords: | organometallics metallacycle photothermal |
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