| 可见光促进合成三氟甲基取代的四氢呋喃和四氢吡喃（英文） |
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| 引用本文： | 王娜,顾强帅,程永峰,李磊,李忠良,郭臻,刘心元.可见光促进合成三氟甲基取代的四氢呋喃和四氢吡喃（英文）[J].有机化学,2019(1):200-206. |
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| 作者姓名： | 王娜 顾强帅 程永峰 李磊 李忠良 郭臻 刘心元 |
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| 作者单位： | 南方科技大学化学系和格拉布斯研究院;太原理工大学材料科学与工程学院新材料界面科学与工程教育部重点实验室;南方科技大学前沿与交叉科学研究院 |
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| 基金项目： | Project supported by the National Natural Science Foundation of China(Nos.21722203,21831002,21801116,and 21572096);the Shenzhen Special Funds for the Development of Biomedicine,Internet,New Energy,and New Material Industries(Nos.JCYJ20170412152435366,JCYJ20170307105638498);the Natural Science Foundation of Guangdong Province(No.2018A030310083);the Shenzhen Nobel Prize Scientists Laboratory Project(No.C17213101)~~ |
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| 摘 要： | 利用相对廉价易得、操控简便的三氟甲基磺酰氯为三氟甲基自由基前体,在可见光催化下通过非活化烯烃的自由基1,2-烷氧基-三氟甲基化反应实现了一系列三氟甲基化的四氢呋喃和四氢吡喃化合物的高效合成.
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| 关 键 词： | 三氟甲基磺酰氯 四氢呋喃 四氢吡喃 可见光 烷氧-三氟甲基化 |
Visible-Light Promoted Preparation of Trifluoromethylated Tetrahydrofuran and Tetrahydropyran |
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| Wang Na,Gu Qiang-Shuai,Cheng Yong-Feng,Li Lei,Li Zhong-Liang,Guo Zhen,Liu Xin-Yuan.Visible-Light Promoted Preparation of Trifluoromethylated Tetrahydrofuran and Tetrahydropyran[J].Chinese Journal of Organic Chemistry,2019(1):200-206. |
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| Authors: | Wang Na Gu Qiang-Shuai Cheng Yong-Feng Li Lei Li Zhong-Liang Guo Zhen Liu Xin-Yuan |
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| Institution: | (Department of Chemistry and Shenzhen Grubbs Institute, Southern University of Science and Technology, Shenzhen 518055;Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, College of Materials Science & Engineering, Taiyuan University of Technology, Shanxi 030024;SUSTech Academy for Advanced Interdisciplinary Studies, Southern University of Science and Technology, Shenzhen 518055) |
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| Abstract: | Wang Na;Gu Qiang-Shuai;Cheng Yong-Feng;Li Lei;Li Zhong-Liang;Guo Zhen;Liu Xin-Yuan(Department of Chemistry and Shenzhen Grubbs Institute, Southern University of Science and Technology, Shenzhen 518055;Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, College of Materials Science & Engineering, Taiyuan University of Technology, Shanxi 030024;SUSTech Academy for Advanced Interdisciplinary Studies, Southern University of Science and Technology, Shenzhen 518055) |
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| Keywords: | trifluoromethanesulfonyl chloride tetrahydrofuran tetrahydropyran visible light alkoxyl-trifluoromethylation |
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