Synthesis and properties of a triarylamine derivative with a coordination site and its copper (II) complex |
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| Affiliation: | 1. Department of Chemistry, Panjab University, Chandigarh 160014, India;2. Department of Botany and Microbiology, Gurukul Kangri University, Haridwar 249404, Uttarakhand, India;1. Department of Chemistry, Yeungnam University, Gyeongsan City, Gyeong-buk 712-749, Republic of Korea;2. Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Republic of Korea;3. Department of Fine Chemistry, Seoul National University of Science and Technology, Seoul 139-743, Republic of Korea;4. Department of Interdisciplinary Bio IT Materials, Seoul National University of Science and Technology, Seoul 139-743, Republic of Korea |
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| Abstract: | A ligand, 4-(bis(2-picolyl)aminomethyl)-4′,4″-dimethyltriphenylamine ((2-py)2TPA) and its copper complex were designed and prepared in order to examine intramolecular interactions of organic cation radical–metal ion. CV measurements of the copper complex showed reversible CuI/CuII and TPA/TPA+· redox couples. The spin–spin interaction in [Cu((2-py)2TPA)Cl]2+ generated upon one electron oxidation of the copper complex was examined by ESR measurements. |
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