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Photoinduced magnetic properties of sequentially deposited thin films of RbjCok[Fe(CN)6]l · nH2O
Institution:1. Department of Physics and Center for Condensed Matter Sciences, University of Florida, P.O. Box 118440, Gainesville, FL 32611-8440, USA;2. Department of Chemistry, University of Florida, Gainesville, FL 32611-7200, USA;1. College of Environmental Science and Engineering, North China Electric Power University, Beijing 102206, PR China;2. Guangdong Provincial Key Laboratory of Radionuclides Pollution Control and Resources, Guangzhou 510006, PR China;3. NAAM Research Group, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia;1. MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China;2. Department of Environmental Engineering, National Chung Hsing University, 250 Kuo-Kuang Road, Taichung, Taiwan;1. Northeast Institute of Geography and Agroecology, Chinese Academy of Sciences, 4888 Shengbei Rd, Changchun 130102, China;2. Shandong Key Laboratory of Eco-Environmental Science for the Yellow River Delta, Binzhou University, No. 391, 5th Yellow River Road, Binzhou City 256603, Shandong Province, China;3. University of Chinese Academy of Sciences, Beijing 100049, China;1. MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001, China;2. Department of Environmental Engineering, National Chung Hsing University, 250 Kuo-Kuang Road, Taichung, Taiwan;1. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada-Unidad Legaria, Instituto Politécnico Nacional, México, D.F., Mexico;2. Instituto Universitario de Tecnología Química CSIC-UPV, Universidad Politécnica de Valencia, Av. De los Naranjos s/n, 46022 Valencia, Spain
Abstract:Using sequential deposition methods, we have generated two different films of RbjCokFe(CN)6]l · nH2O for magneto-optical studies. The synthesis protocol was intentionally varied in order to generate samples with different degrees of surface homogeneity. As a consequence, film 1 possessed a powder-like rough surface, while film 2 was a smooth, quasi-two-dimensional film. Upon irradiation at 5 K with an external magnetic field of 200 G perpendicular to the film surface, the magnetization of film 1 increased, whereas the magnetization of film 2 decreased. This contrasting behavior is consistent with a dipolar field model describing the phenomena and is related to the novel anisotropy of the photoinduced magnetism in film 2, where the photoinduced magnetization increases or decreases depending on the orientation of the film with respect to the external field.
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