Solid solutions: An efficient way to control the temperature of spin transition in heterospin crystals MxCu1 − x(hfac)2L (M = Mn,Ni, Co; L = nitronyl nitroxide) |
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| Institution: | 1. International Tomography Center, Laboratory of Multispin Coordination Compounds, Russian Academy of Sciences, Institutskaya Str. 3A, 630090 Novosibirsk, Russia;2. Novosibirsk State University, Pirogova Str. 2, 630090 Novosibirsk, Russia;1. Research Scholar, Department of Chemistry, National Institute of Technology, Tiruchirappalli 620015, Tamil Nadu, India;2. Research Scholar, Department of Chemistry, National Institute of Technology, Tiruchirappalli 620015, Tamil Nadu, India;3. Department of Chemistry, National Institute of Technology, Tiruchirappalli 620015, Tamil Nadu, India;1. Department of Chemistry, Shanxi Agricultural University, Taigu Shanxi 030801, PR China;2. Department of Chemistry, Nankai University, Tianjin 300071, PR China;3. Tianjin Key Laboratory on Technologies Enabling Development of Clinical Therapeutics and Diagnostics (Theranostics), School of Pharmacy, Tianjin Medical University, Tianjin 300070, PR China;1. Depto. de Sistemas Biológicos, Universidad Autónoma Metropolitana Unidad Xochimilco Ciudad de México C.P, 04960, Mexico;2. Unidad de Experimentación Animal, Facultad de Química, Universidad Nacional Autónoma de México (UNAM), Ciudad Universitaria, DF 04510, Mexico;3. Depto. Química Inorgánica y Nuclear, Facultad de Química, Universidad Nacional Autónoma de México (UNAM), Ciudad Universitaria, DF 04510, Mexico;4. Depto. Farmacia, Facultad de Química, Universidad Nacional Autónoma de México (UNAM), Ciudad Universitaria, DF 04510, Mexico;1. N.N. Vorozhtsov Institute of Organic Chemistry, Russian Academy of Sciences, Novosibirsk 630090, Russia;2. National Research University – Novosibirsk State University, Novosibirsk 630090, Russia;1. Chemistry Department, Faculty of Applied Sciences, Umm Al-Qura University, Saudi Arabia;2. Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt |
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| Abstract: | A series of mixed-metal solid solutions MxCu1 − x(hfac)2L (M = Mn, Ni, and Co) liable to undergo thermally induced spin transitions have been synthesized. The structure and magnetic properties of the compounds have been investigated. By varying the metal to be incorporated in the complex (Mn, Ni, or Co) and the value of x, one can control the character of the magnetic anomaly. |
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