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Mössbauer effect study of nonstoichiometric CoNiZn ferrites
Authors:D Hanžel  S Beseničar  D Hanzel
Institution:(1) J. Stefan Institute, E. Kardelj University, Ljubljana, Yugoslavia;(2) Faculty of Natural Sciences and Technology, E. Kardelj University, Ljubljana, Yugoslavia
Abstract:The existence of fast electron exchange between pairs of Fe3+?Fe2+ ions was detected in Mössbauer spectra of non-stoichiometric CoNiZn ferrites containing an excess of Fe2O3. Analysis of spectra from a number of samples of various preparations showed correlation of bulk magnetic properties with hyperfine parameters of ferric ions at octahedral sites in the spinel structure.
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