Beta-elimination of a phosphonate group from an alkoxy radical: an intramolecular acylation approach using an acylphosphonate as a carbonyl group acceptor |
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| Authors: | Kim Sunggak Cho Chang Ho Lim Chae Jo |
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| Institution: | Center for Molecular Design and Synthesis and Department of Chemistry, School of Molecular Science, Korea Advanced Institute of Science and Technology, Taejon 305-701, Korea. skim@kaist.ac.kr |
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| Abstract: | On the basis of facile beta-elimination of a phosphonate group from an alkoxy radical, intramolecular acylation reaction has been developed, in which an acylphosphonate is used as an excellent carbonyl group radical acceptor. |
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