Macroscopic capillarity without a constitutive capillary pressure function |
| |
Affiliation: | 1. ICP, Universität Stuttgart, 70569 Stuttgart, Germany;2. Institut für Physik, Universität Mainz, 55099 Mainz, Germany;1. INPT, UPS, IMFT (Institut de Mécanique des Fluides de Toulouse), Université de Toulouse, Allée Camille Soula, F-31400 Toulouse, France;2. CNRS, IMFT, F-31400 Toulouse, France;3. Fuel Cell Components Laboratory (LCPEM), LITEN, CEA, 17 rue des Martyrs, 38000 Grenoble, France;1. Dipartimento di Chimica e Farmacia, University of Sassari, Italy;2. POLCOMING Department, Section of Information Engineering, University of Sassari, Italy;3. Istituto Nazionale di Fisica Nucleare, Sezione di Cagliari, Italy |
| |
Abstract: | This paper challenges the foundations of the macroscopic capillary pressure concept. The capillary pressure function, as it is traditionally assumed in the constitutive theory of two-phase immiscible displacement in porous media, relates the pressure difference between nonwetting and wetting fluid to the saturation of the wetting fluid. The traditional capillary pressure function neglects the fundamental difference between percolating and nonpercolating fluid regions as first emphasized in R. Hilfer [Macroscopic equations of motion for two phase flow in porous media, Phys. Rev. E 58 (1998) 2090]. The theoretical approach proposed here starts from residual saturations as the volume fractions of nonpercolating phases. The resulting equations of motion open the possibility to describe flow processes where drainage and imbibition occur simultaneously. The theory predicts hysteresis and process dependence of capillary phenomena. The traditional theory is recovered as a special case in the residual decoupling approximation. Explicit calculations are presented for quasistatic equilibrium profiles near hydrostatic equilibrium. The results are found to agree with experiment. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|