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LaCo13基金属间化合物的磁性能和储氢性能
引用本文:李蓉,黄巍,吴建民,周少雄. LaCo13基金属间化合物的磁性能和储氢性能[J]. 中国稀土学报, 2007, 25(5): 513-521
作者姓名:李蓉  黄巍  吴建民  周少雄
作者单位:1. 钢铁研究总院功能材料所,北京,100081
2. 安泰科技股份有限公司,北京,100081
基金项目:国家自然科学基金资助项目(50371018)
摘    要:对LaCo13基金属间化合物在磁致冷材料和储氢材料领域中的应用进行了综述,总结了该系化合物的成相规律、替换元素对相稳定性的影响,讨论了近期的研究进展及存在的问题。作为磁致冷材料应用时,LaCo13基金属间化合物在室温具有巨大磁熵变,而作为储氢合金时该系化合物表现出优异的高温电化学容量。虽然在磁致冷和储氢材料领域尚未对LaCo13基金属间化合物进行实用开发,但作为新型绿色能源材料已经展示出良好的应用前景。

关 键 词:LaCo13基金属间化合物  磁性能  储氢性能  相结构  稀土
文章编号:1000-4343(2007)05-0513-09
修稿时间:2007-03-01

Magnetic and Hydrogen Storage Properties for LaCo13-based Intermetallic Compounds
Li Rong,Huang Wei,Wu Jianmin,Zhou Shaoxiong. Magnetic and Hydrogen Storage Properties for LaCo13-based Intermetallic Compounds[J]. Journal of the Chinese Society of Rare Earths, 2007, 25(5): 513-521
Authors:Li Rong  Huang Wei  Wu Jianmin  Zhou Shaoxiong
Abstract:The application of LaCo13-based intermetallic compounds as magnetic refrigeration and hydrogen storage materials was reviewed.Phase forming rules and the influence of substituted elements on phase stability for LaCo13-based intermetallic compounds were included.The latest research progress and disadvantages of LaCo13-based intermetallic compounds were discussed.The typical characteristics of LaCo13-based intermetallic compounds have large magnetic entropy change at ambient temperature as magnetic refrigeration material and good high temperature electrochemical capacity as hydrogen storage alloys.LaCo13-based intermetallic compounds are novel green energy materials with good outlook,although they are still not used practically.
Keywords:LaCo13-based intermetallic compounds  magnetic performance  hydrogen storage performance  phase structure  rare earths
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