Microwave spectra in the v8 and 2v8 states of methyl isocyanide and its 15N derivative |
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Authors: | M Godon A Bauer |
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Institution: | Laboratoire de Spectroscopie Hertzienne, Laboratoire Associé au C.N.R.S., Université de Lille I, B.P. 36, 59650 Villeneuve d''AscqFrance |
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Abstract: | A new analysis of the microwave spectra of methyl isocyanide CH314NC in the v8 and 2v8 states is obtained by the use of more experimental data and calculations by diagonalization of the energy matrix. The same spectra for the 15N derivative have been observed, and their analysis reveals resonant effects still stronger than for CH314NC. Sets of rotation and rotation-vibration constants are reported for both molecules. |
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