Structural, Spectroscopic and Thermal Characterisation of bis (dibenzoylmethanato)Cd(II) Adducts with Dimethylsulfoxide and Water |
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Authors: | Ivan Halasz Michaela Horvat Tomislav Biljan Ernest Meštrović |
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Institution: | (1) Chemistry Department, Faculty of Science, University of Zagreb, Horvatovac 102a, 10000 Zagreb, Croatia;(2) PLIVA Croatia Ltd., Research and Development, Prilaz baruna Filipovića 29, 10000 Zagreb, Croatia |
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Abstract: | Abstract Adducts of cadmium(II) dibenzoylmethate, Cd(dbm)2X2 (X = DMSO, H2O) were synthesized and analyzed by thermogravimetric analysis (TGA), differential-scanning calorimetry (DSC), hot-stage microscopy
(HSM), single crystal X-ray diffraction, FTIR and Raman spectroscopy, and elemental analysis. Products obtained by thermal
decomposition of the two Cd(II) complexes in oxygen, were used for quantitative analysis of cadmium in the adduct molecules.
Single-crystal X-ray diffraction analysis of the DMSO adduct revealed that it has cis configuration. The DMSO adduct crystallizes in P21/a space group, a = 17.2494(6) ?, b = 8.3251(4) ?, c = 22.2746(9) ?, β = 93.836(3)°, V = 3191.53(7) ?3, Z = 4.
Graphical abstract
Structural, Spectroscopic and Thermal Characterisation of bis (dibenzoylmethanato)Cd(II) Adducts With Dimethylsulfoxide and
Water
Ivan Halasz, Michaela Horvat, Tomislav Biljan, Ernest Meštrović
Two adducts of bis(dibenzoylmethanato)Cd(II), Cd(dbm)2X2 (X = DMSO, H2O) have been synthesized and characterized.
![MediaObjects/10870_2008_9392_Figa_HTML.gif](/content/e5r64m1571164562/MediaObjects/10870_2008_9392_Figa_HTML.gif) |
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Keywords: | Hot-stage microscopy Thermogravimetric analysis Differential scanning calorimetry FTIR spectroscopy Raman spectroscopy Adduct Cadmium(II) β -diketone |
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