Recognition-mediated assembly of nanoparticles into micellar structures with diblock copolymers |
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| Authors: | Frankamp Benjamin L Uzun Oktay Ilhan Faysal Boal Andrew K Rotello Vincent M |
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| Affiliation: | Department of Chemistry, University of Massachusetts, Amherst, Massachusetts 01003, USA. |
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| Abstract: | Polystyrene-based diblock copolymers, featuring diaminotriazine functionality on one of the blocks were used to assemble complementary uracil-functionalized nanoparticles into micellar aggregates. The size of these self-assembled aggregates was controlled by block length, as determined in solution (using dynamic light scattering), and in thin films (using transmission electron microscopy). |
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