Isomerization of alkenes in the presence of Pd(acac)2-BF3OEt2 catalytic system |
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Authors: | V S Tkach D S Suslov M Gomboogiin G V Ratovskii F K Shmidt |
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Institution: | (1) Irkutsk State University, Irkutsk, Russia;(2) Mongolian State University, Ulan-Bator, Mongolian Republic |
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Abstract: | Positional isomerization of alkenes was studied in the presence of Pd(acac)2 + 20BF3OEt2 catalytic system. The reactivity of alkenes decreases in the following order: 1-hexene > 1-heptene > 2-methyl-1-pentene > 4-methyl-2-pentene (cis + trans). |
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